Expanded Porphyrins: More Confusion All the Time | Zendy

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Expanded Porphyrins: More Confusion All the Time

Author(s) -

D'Souza Francis

Publication year - 2015

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201501046

Subject(s) - confusion , reactivity (psychology) , pyrrole , yield (engineering) , chemistry , closure (psychology) , porphyrin , ring (chemistry) , combinatorial chemistry , terminal (telecommunication) , photochemistry , organic chemistry , computer science , materials science , psychology , telecommunications , political science , medicine , psychoanalysis , law , alternative medicine , pathology , metallurgy

Confusion leads to cooperative reactivity : Oxidative ring‐closure reactions of oligopyrranes containing two terminal confused pyrroles yield expanded porphyrinoids, which show cooperative reactivity between the directly linked confused pyrroles. These transformations constitute a new method for the synthesis of novel porphyrinoids with unconventional pyrrole linking modes and unique properties.

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