Halogen‐Bond‐Assisted Guest Inclusion in a Synthetic Cavity | Zendy

Takezawa Hiroki | Zendy; Murase Takashi | Zendy; Resnati Giuseppe | Zendy; Metrangolo Pierangelo | Zendy; Fujita Makoto | Zendy

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Halogen‐Bond‐Assisted Guest Inclusion in a Synthetic Cavity

Author(s) -

Takezawa Hiroki,

Murase Takashi,

Resnati Giuseppe,

Metrangolo Pierangelo,

Fujita Makoto

Publication year - 2015

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201500994

Subject(s) - inclusion (mineral) , bond , halogen bond , chemistry , nanotechnology , halogen , materials science , business , mineralogy , organic chemistry , alkyl , finance

The confined space inside a self‐assembled cage enhanced halogen bonding (XB) between iodoperfluorocarbons (XB donors) and NO 3 − anions or H 2 O molecules (XB acceptors), as confirmed by NMR spectroscopy in solution and by X‐ray crystallography in the solid state. The cavity also bound an XB donor–acceptor pair, C 6 F 3 I 3 and C 6 H 5 NMe 2 , in a selective pairwise fashion.

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