Fe II  Spin‐Crossover Phenomenon in the Pentadecanuclear {Fe 9 [Re(CN) 8 ] 6 } Spherical Cluster | Zendy

Chorazy Szymon | Zendy; Podgajny Robert | Zendy; Nakabayashi Koji | Zendy; Stanek Jan | Zendy; Rams Michał | Zendy; Sieklucka Barbara | Zendy; Ohkoshi Shinichi | Zendy

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Fe II Spin‐Crossover Phenomenon in the Pentadecanuclear {Fe 9 [Re(CN) 8 ] 6 } Spherical Cluster

Author(s) -

Chorazy Szymon,

Podgajny Robert,

Nakabayashi Koji,

Stanek Jan,

Rams Michał,

Sieklucka Barbara,

Ohkoshi Shinichi

Publication year - 2015

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201500288

Subject(s) - spin crossover , cluster (spacecraft) , ion , crystallography , molecule , chemistry , spin (aerodynamics) , center (category theory) , materials science , phase (matter) , physics , organic chemistry , computer science , programming language , thermodynamics

The self‐assembly of iron(II) ions with rare octacyanidorhenate(V) metalloligands in a methanolic solution results in the formation of a nanometric pentadecanuclear {Fe II 9 [Re V (CN) 8 ] 6 (MeOH) 24 }⋅10 MeOH ( 1 ) molecule with a six‐capped body‐centered cubic topology. The cluster demonstrates a thermally‐induced spin‐crossover phase transition at T 1/2 =195 K which occurs selectively for a single Fe II ion embedded in the center of a cluster core.

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