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Visible‐Light‐Mediated Chan–Lam Coupling Reactions of Aryl Boronic Acids and Aniline Derivatives
Author(s) -
Yoo WooJin,
Tsukamoto Tatsuhiro,
Kobayashi Shū
Publication year - 2015
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201500074
Subject(s) - aniline , aryl , chemistry , photoredox catalysis , boronic acid , catalysis , oxidative phosphorylation , suzuki reaction , oxidative coupling of methane , substrate (aquarium) , combinatorial chemistry , photochemistry , organic chemistry , photocatalysis , biochemistry , alkyl , oceanography , geology
Abstract The copper(II)‐catalyzed aerobic oxidative coupling reaction between aryl boronic acids and aniline derivatives was found to be improved significantly under visible‐light‐mediated photoredox catalysis. The substrate scope of this oxidative Chan–Lam reaction was thus expanded to include electron‐deficient aryl boronic acids as viable starting materials.