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A Functionalized Ag 2 S Molecular Architecture: Facile Assembly of the Atomically Precise Ferrocene‐Decorated Nanocluster [Ag 74 S 19 (dppp) 6 (fc(C{O}OCH 2 CH 2 S) 2 ) 18 ]
Author(s) -
Liu Yiyi,
Khalili Najafabadi Bahareh,
Azizpoor Fard Mahmood,
Corrigan John F.
Publication year - 2015
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201411944
Subject(s) - ferrocene , yield (engineering) , reagent , dithiol , salt (chemistry) , chemistry , rhenium , crystallography , materials science , nanotechnology , inorganic chemistry , organic chemistry , electrochemistry , metallurgy , electrode
A ferrocene‐based dithiol 1,1′‐[fc(C{O}OCH 2 CH 2 SH) 2 ] has been prepared and treated with a Ag I salt to form the stable dithiolate compound [fc(C{O}OCH 2 CH 2 SAg) 2 ] n (fc=[Fe(η 5 ‐C 5 H 4 ) 2 ]). This is used as a reagent for the preparation of the nanocluster [Ag 74 S 19 (dppp) 6 (fc(C{O}OCH 2 CH 2 S) 2 ) 18 ] which was obtained in good yield (dppp=1,3‐bis(diphenylphosphino)propane).