Iron‐Catalyzed Asymmetric Hydrosilylation of 1,1‐Disubstituted Alkenes | Zendy

Chen Jianhui | Zendy; Cheng Biao | Zendy; Cao Minyi | Zendy; Lu Zhan | Zendy

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Iron‐Catalyzed Asymmetric Hydrosilylation of 1,1‐Disubstituted Alkenes

Author(s) -

Chen Jianhui,

Cheng Biao,

Cao Minyi,

Lu Zhan

Publication year - 2015

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201411884

Subject(s) - hydrosilylation , markovnikov's rule , enantioselective synthesis , silanes , chemistry , oxazoline , catalysis , derivatization , organic chemistry , phenol , aryl , regioselectivity , silane , alkyl , high performance liquid chromatography

The highly regio‐ and enantioselective iron‐catalyzed anti‐Markovnikov hydrosilylation of 1,1‐disubstituted aryl alkenes was developed using iminopyridine oxazoline ligands to afford chiral organosilanes. Additional derivatization of these products lead to chiral organosilanols, cyclic silanes, phenol derivatives, and 3‐substituted 2,3‐dihydrobenzofurans.

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