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Inside Back Cover: The Reactivities of Iminoboranes with Carbenes: BN Isosteres of Carbene–Alkyne Adducts (Angew. Chem. Int. Ed. 5/2015)
Author(s) -
Braunschweig Holger,
Ewing William C.,
Geetharani K.,
Schäfer Marius
Publication year - 2015
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201411644
Subject(s) - carbene , adduct , alkyne , chemistry , bicyclic molecule , lewis acids and bases , boranes , frustrated lewis pair , stereochemistry , organic chemistry , boron , catalysis
The reactions of imino boranes and singlet carbenes display expected as well as unexpected rectivity patterns. In their Communication on page 1662 ff., H. Braunschweig and co‐workers report the formation of an iminoborane–carbene Lewis acid–base adduct, an aminoborane‐functionalized carbene, and a bicyclic azaborolidine from the reactions of three different carbenes with the same iminoborane.