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Redox‐Active NO x Ligands in Palladium‐Mediated Processes
Author(s) -
Fairlamb Ian J. S.
Publication year - 2015
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201411487
Subject(s) - palladium , alkene , redox , surface modification , wacker process , chemistry , combinatorial chemistry , catalysis , organic chemistry
This Minireview highlights the redox and non‐innocent behavior of NO x ligands (x=1, 2, or 3) in selected Pd‐mediated processes, for example, alkene and aromatic oxidation processes. A focus is placed on mechanistic understanding and linking recent transformations, such as CH bond activation/functionalization and Wacker oxidation, with previous work on the functionalization of aromatics and alkenes by Pd II salts.