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Cooperation between Transition Metals and Lewis Acids: A Way To Activate H 2 and HE bonds
Author(s) -
Devillard Marc,
Bouhadir Ghenwa,
Bourissou Didier
Publication year - 2015
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201410781
Subject(s) - lewis acids and bases , borane , transition metal , chemistry , frustrated lewis pair , coordination sphere , crystallography , stereochemistry , catalysis , organic chemistry , crystal structure
The presence of a Lewis acid, typically a borane, in the coordination sphere of transition metals (Ni, Fe, Pt) offers a new way to activate H 2 and strong HE (E=Si, C) bonds.