Reactions of Difunctional Electrophiles with Functionalized Aryllithium Compounds: Remarkable Chemoselectivity by Flash Chemistry | Zendy

Nagaki Aiichiro | Zendy; Imai Keita | Zendy; Ishiuchi Satoshi | Zendy; Yoshida Junichi | Zendy

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Reactions of Difunctional Electrophiles with Functionalized Aryllithium Compounds: Remarkable Chemoselectivity by Flash Chemistry

Author(s) -

Nagaki Aiichiro,

Imai Keita,

Ishiuchi Satoshi,

Yoshida Junichi

Publication year - 2015

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201410717

Subject(s) - chemoselectivity , electrophile , chemistry , combinatorial chemistry , flash (photography) , organic chemistry , catalysis , art , visual arts

Flash chemistry using flow microreactors enables highly chemoselective reactions of difunctional electrophiles with functionalized aryllithium compounds by virtue of extremely fast micromixing. The approach serves as a powerful method for protecting‐group‐free synthesis using organolithium compounds and opens a new possibility in the synthesis of polyfunctional organic molecules.

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