Cooperative Lewis Pairs Based on Late Transition Metals: Activation of Small Molecules by Platinum(0) and B(C 6 F 5 ) 3 | Zendy

Forrest Sebastian J. K. | Zendy; Clifton Jamie | Zendy; Fey Natalie | Zendy; Pringle Paul G. | Zendy; Sparkes Hazel A. | Zendy; Wass Duncan F. | Zendy

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Cooperative Lewis Pairs Based on Late Transition Metals: Activation of Small Molecules by Platinum(0) and B(C 6 F 5 ) 3

Author(s) -

Forrest Sebastian J. K.,

Clifton Jamie,

Fey Natalie,

Pringle Paul G.,

Sparkes Hazel A.,

Wass Duncan F.

Publication year - 2015

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201409872

Subject(s) - frustrated lewis pair , lewis acids and bases , platinum , molecule , chemistry , transition metal , ligand (biochemistry) , small molecule , crystallography , stereochemistry , catalysis , organic chemistry , biochemistry , receptor

A Lewis basic platinum(0)–CO complex supported by a diphosphine ligand and B(C 6 F 5 ) 3 act cooperatively, in a manner reminiscent of a frustrated Lewis pair, to activate small molecules such as hydrogen, CO 2 , and ethene. This cooperative Lewis pair facilitates the coupling of CO and ethene in a new way.

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