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Modulation of Benzene or Naphthalene Binding to Palladium Cluster Sites by the Backside‐Ligand Effect
Author(s) -
Ishikawa Yuki,
Kimura Seita,
Takase Kohei,
Yamamoto Koji,
Kurashige Yuki,
Yanai Takeshi,
Murahashi Tetsuro
Publication year - 2015
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201409499
Subject(s) - naphthalene , ligand (biochemistry) , palladium , chemistry , benzene , cluster (spacecraft) , cyclooctatetraene , metal , substrate (aquarium) , reactivity (psychology) , photochemistry , stereochemistry , catalysis , organic chemistry , molecule , receptor , biochemistry , medicine , oceanography , alternative medicine , pathology , computer science , programming language , geology
The backside‐ligand modulation strategy to enhance the substrate binding property of Pd clusters is reported. The benzene or naphthalene binding ability of Pd 3 or Pd 4 clusters is enhanced significantly by the backside cyclooctatetraene ligand, leading to the formation of the first solution‐stable benzene‐ or naphthalene Pd clusters. The present results imply that the ligand design of the metal clusters, especially for the backside ligand of the metal cluster site, is crucial to acquire a desired reactivity of metal clusters.