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Inside Back Cover: Cluster Linker Approach: Preparation of a Luminescent Porous Framework with NbO Topology by Linking Silver Ions with Gold(I) Clusters (Angew. Chem. Int. Ed. 47/2014)
Author(s) -
Lei Zhen,
Pei XiaoLi,
Jiang ZhanGuo,
Wang QuanMing
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201408887
Subject(s) - luminescence , bifunctional , natural bond orbital , cluster (spacecraft) , linker , cover (algebra) , materials science , porosity , topology (electrical circuits) , ion , nanotechnology , chemistry , optoelectronics , computer science , molecule , organic chemistry , computer network , engineering , composite material , mechanical engineering , electrical engineering , operating system , catalysis
A “cluster linker” approach has been developed for the construction of a cluster‐based metal–organic framework, as described by Q.‐M. Wang and co‐workers in their Communication on page 12771 ff. The luminescence of the cluster is introduced into the bifunctional porous framework, which has NbO topology. The luminescent porous material thus formed displays enhanced emission and solvatochromic behavior.