A 3‐Pyridyl‐5,15‐Diazaporphyrin Nickel(II) Complex as a Bidentate Metalloligand for Transition Metals | Zendy

Yamaji Ayaka | Zendy; Shin JiYoung | Zendy; Miyake Yoshihiro | Zendy; Shinokubo Hiroshi | Zendy

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A 3‐Pyridyl‐5,15‐Diazaporphyrin Nickel(II) Complex as a Bidentate Metalloligand for Transition Metals

Author(s) -

Yamaji Ayaka,

Shin JiYoung,

Miyake Yoshihiro,

Shinokubo Hiroshi

Publication year - 2014

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201408852

Subject(s) - denticity , chemistry , rhenium , nickel , transition metal , crystallography , metal , platinum , ruthenium , absorption spectroscopy , ligand (biochemistry) , inorganic chemistry , crystal structure , organic chemistry , catalysis , biochemistry , physics , receptor , quantum mechanics

3‐Pyridyl‐5,15‐diazaporphyrin nickel(II) serves as a bidentate metalloligand for platinum(II), ruthenium(II), and rhenium(I) metal centers. Single‐crystal X‐ray diffraction analysis of these metal complexes unambiguously reveals the presence of a dative bond between the outer metal center and the meso ‐nitrogen atom. The UV/Vis absorption spectra of the complexes show substantially red‐shifted bands which are perturbed by outer‐metal coordination. This is due to the contribution of metal‐to‐ligand charge transfer interactions.

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