Ligand‐Promoted  ortho ‐CH Amination with Pd Catalysts | Zendy

Zhu Dajian | Zendy; Yang Guoqiang | Zendy; He Jian | Zendy; Chu Ling | Zendy; Chen Gang | Zendy; Gong Wei | Zendy; Chen Ke | Zendy; Eastgate Martin D. | Zendy; Yu JinQuan | Zendy

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Ligand‐Promoted ortho ‐CH Amination with Pd Catalysts

Author(s) -

Zhu Dajian,

Yang Guoqiang,

He Jian,

Chu Ling,

Chen Gang,

Gong Wei,

Chen Ke,

Eastgate Martin D.,

Yu JinQuan

Publication year - 2015

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201408651

Subject(s) - amination , ligand (biochemistry) , catalysis , chemistry , combinatorial chemistry , medicinal chemistry , organic chemistry , receptor , biochemistry

2,4,6‐Trimethoxypyridine is identified as an efficient ligand for promoting a Pd‐catalyzed ortho‐CH amination of both benzamides and triflyl‐protected benzylamines. This finding provides guidance for the development of ligands that can improve or enable Pd II ‐catalyzed C sp 2H activation reactions directed by weakly coordinating functional groups.

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