A Carbene‐Rich but Carbonyl‐Poor [Ir 6 (IMe) 8 (CO) 2 H 14 ] 2+  Polyhydride Cluster as a Deactivation Product from Catalytic Glycerol Dehydrogenation | Zendy

Campos Jesús | Zendy; Sharninghausen Liam S. | Zendy; Crabtree Robert H. | Zendy; Balcells David | Zendy

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A Carbene‐Rich but Carbonyl‐Poor [Ir 6 (IMe) 8 (CO) 2 H 14 ] 2+ Polyhydride Cluster as a Deactivation Product from Catalytic Glycerol Dehydrogenation

Author(s) -

Campos Jesús,

Sharninghausen Liam S.,

Crabtree Robert H.,

Balcells David

Publication year - 2014

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201407997

Subject(s) - carbene , cluster (spacecraft) , dehydrogenation , spectroscopy , chemistry , catalysis , nuclear magnetic resonance spectroscopy , fourier transform infrared spectroscopy , crystallography , product (mathematics) , infrared spectroscopy , stereochemistry , physics , organic chemistry , quantum mechanics , computer science , programming language , geometry , mathematics

The title cluster, a deactivation product in the catalytic dehydrogenation of glycerol, was characterized by XRD, DFT calculations, HRMS, FTIR spectroscopy, and NMR spectroscopy. Experimental/computational studies located the 14 H ligands, and all 1 H and 13 C{ 1 H} NMR resonances were assigned. The structure contains an unprecedented Ir 6 H 14 core with two CO and eight IMe ligands.

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