A Palladium Nanoparticle–Nanomicelle Combination for the Stereoselective Semihydrogenation of Alkynes in Water at Room Temperature | Zendy

Slack Eric D. | Zendy; Gabriel Christopher M. | Zendy; Lipshutz Bruce H. | Zendy

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A Palladium Nanoparticle–Nanomicelle Combination for the Stereoselective Semihydrogenation of Alkynes in Water at Room Temperature

Author(s) -

Slack Eric D.,

Gabriel Christopher M.,

Lipshutz Bruce H.

Publication year - 2014

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201407723

Subject(s) - palladium , nanoparticle , stereoselectivity , materials science , nanotechnology , combinatorial chemistry , chemical engineering , chemistry , organic chemistry , catalysis , engineering

The addition of NaBH 4 to Pd(OAc) 2 in water containing nanomicelles leads to the generation of H 2 and Pd nanoparticles. Subsequent reduction of disubstituted alkynes affords Z ‐alkenes in high yields. These reactions are general, take place in water at ambient temperatures, and offer recycling of the aqueous reaction mixture along with low overall E Factors.

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