Synthesis of Aryldiazoacetates through Palladium(0)‐Catalyzed Deacylative Cross‐Coupling of Aryl Iodides with Acyldiazoacetates | Zendy

Ye Fei | Zendy; Wang Chengpeng | Zendy; Zhang Yan | Zendy; Wang Jianbo | Zendy

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Synthesis of Aryldiazoacetates through Palladium(0)‐Catalyzed Deacylative Cross‐Coupling of Aryl Iodides with Acyldiazoacetates

Author(s) -

Ye Fei,

Wang Chengpeng,

Zhang Yan,

Wang Jianbo

Publication year - 2014

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201407653

Subject(s) - aryl , palladium , catalysis , coupling reaction , coupling (piping) , combinatorial chemistry , acceptor , chemistry , polymer chemistry , organic chemistry , materials science , physics , metallurgy , alkyl , condensed matter physics

Palladium(0)‐catalyzed deacylative cross‐coupling of aryl iodides and acyldiazocarbonyl compounds can be achieved at room temperature under mild reaction conditions. The coupling reaction represents a highly efficient and general method for the synthesis of aryldiazocarbonyl compounds, which have found wide and increasing applications as precursors for generating donor/acceptor‐substituted metallocarbenes.

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