A  cis ‐Divacant Octahedral and Mononuclear Iron(IV) Imide | Zendy

Searles Keith | Zendy; Fortier Skye | Zendy; Khusniyarov Marat M. | Zendy; Carroll Patrick J. | Zendy; Sutter Jörg | Zendy; Meyer Karsten | Zendy; Mindiola Daniel J. | Zendy; Caulton Kenneth G. | Zendy

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A cis ‐Divacant Octahedral and Mononuclear Iron(IV) Imide

Author(s) -

Searles Keith,

Fortier Skye,

Khusniyarov Marat M.,

Carroll Patrick J.,

Sutter Jörg,

Meyer Karsten,

Mindiola Daniel J.,

Caulton Kenneth G.

Publication year - 2014

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201407156

Subject(s) - imide , octahedron , pyridine , chemistry , redox , ligand (biochemistry) , electron paramagnetic resonance , crystallography , paramagnetism , medicinal chemistry , inorganic chemistry , crystal structure , polymer chemistry , nuclear magnetic resonance , physics , condensed matter physics , biochemistry , receptor

A rare, low‐spin Fe IV imide complex [(pyrr 2 py)FeNAd] (pyrr 2 py 2− =bis(pyrrolyl)pyridine; Ad=1‐adamantyl) confined to a cis‐divacant octahedral geometry, was prepared by reduction of N 3 Ad by the Fe II precursor [(pyrr 2 py)Fe(OEt 2 )]. The imide complex is low‐spin with temperature‐independent paramagnetism. In comparison to an authentic Fe III complex, such as [(pyrr 2 py)FeCl], the pyrr 2 py 2− ligand is virtually redox innocent.

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