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Tuning the Selectivity of Photocatalytic Synthetic Reactions Using Modified TiO 2 Nanotubes
Author(s) -
Tripathy Jyotsna,
Lee Kiyoung,
Schmuki Patrik
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201406324
Subject(s) - photocatalysis , selectivity , benzaldehyde , anatase , benzoic acid , materials science , toluene , rutile , catalysis , chemical engineering , photochemistry , nanotechnology , chemistry , organic chemistry , engineering
Differently modified TiO 2 nanotubes were used to achieve a drastic change in the selectivity of a photocatalytic reaction. For the photocatalytic oxidation of toluene, depending on the electronic properties of TiO 2 (anatase, rutile, Ru‐doped), a strong change in the main reaction product (namely benzoic acid versus benzaldehyde) can be achieved, and certain undesired reaction pathways can be completely shut down.