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Control of Silver(I)–Dialkyl Chalcogenide Coordination by a Synthetic Cavity
Author(s) -
Kohyama Yuh,
Murase Takashi,
Fujita Makoto
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201406224
Subject(s) - chalcogenide , palladium , ligand (biochemistry) , coordination complex , metal , triazine , molecule , chemistry , crystallography , polymer chemistry , organic chemistry , receptor , biochemistry , catalysis
The discrete cavity of a self‐assembled palladium–tris(4‐pyridyl)triazine cage dictates the ratio of metal, ligand, and a non‐coordinative molecule in the formation of silver(I)–dialkyl chalcogenide (Et, n Bu; S, Se) complexes and defines their coordination arrangement.