Inside Cover: Syntheses, Structures, and Reactivities of Two Chalcogen‐Stabilized Carbones (Angew. Chem. Int. Ed. 36/2014) | Zendy

Morosaki Tomohito | Zendy; Suzuki Tsubasa | Zendy; Wang WeiWei | Zendy; Nagase Shigeru | Zendy; Fujii Takayoshi | Zendy

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Inside Cover: Syntheses, Structures, and Reactivities of Two Chalcogen‐Stabilized Carbones (Angew. Chem. Int. Ed. 36/2014)

Author(s) -

Morosaki Tomohito,

Suzuki Tsubasa,

Wang WeiWei,

Nagase Shigeru,

Fujii Takayoshi

Publication year - 2014

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201406155

Subject(s) - dication , int , chalcogen , protonation , cover (algebra) , chemistry , stereochemistry , crystallography , ion , organic chemistry , computer science , engineering , mechanical engineering , operating system

New carbones of the type Ph 2 E→C←SPh 2 (NMe) (E=S or Se) were synthesized and characterized. T. Fujii et al. show in their Communication on page 9569 ff. that the double protonation of Ph 2 Se→C←SPh 2 (NMe) gives a dication, whereas a C‐metalated trication is obtained with silver(I). These reactions constitute the first experimental evidence for a carbodichalcogenurane behaving as a four‐electron donor ligand.

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