Metastable Ionic Diodes Derived from an Amine‐Based Polymer of Intrinsic Microporosity | Zendy

Madrid Elena | Zendy; Rong Yuanyang | Zendy; Carta Mariolino | Zendy; McKeown Neil B. | Zendy; MalpassEvans Richard | Zendy; Attard Gary A. | Zendy; Clarke Tomos J. | Zendy; Taylor Stuart H. | Zendy; Long YiTao | Zendy; Marken Frank | Zendy

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Metastable Ionic Diodes Derived from an Amine‐Based Polymer of Intrinsic Microporosity

Author(s) -

Madrid Elena,

Rong Yuanyang,

Carta Mariolino,

McKeown Neil B.,

MalpassEvans Richard,

Attard Gary A.,

Clarke Tomos J.,

Taylor Stuart H.,

Long YiTao,

Marken Frank

Publication year - 2014

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201405755

Subject(s) - ionic bonding , amine gas treating , metastability , polymer , materials science , electrolyte , polymerization , bistability , chemical engineering , polymer chemistry , diode , base (topology) , chemistry , ion , organic chemistry , electrode , composite material , optoelectronics , mathematical analysis , mathematics , engineering

A highly rigid amine‐based polymer of intrinsic microporosity (PIM), prepared by a polymerization reaction involving the formation of Tröger’s base, is demonstrated to act as an ionic diode with electrolyte‐dependent bistable switchable states.

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