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Metastable Ionic Diodes Derived from an Amine‐Based Polymer of Intrinsic Microporosity
Author(s) -
Madrid Elena,
Rong Yuanyang,
Carta Mariolino,
McKeown Neil B.,
MalpassEvans Richard,
Attard Gary A.,
Clarke Tomos J.,
Taylor Stuart H.,
Long YiTao,
Marken Frank
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201405755
Subject(s) - ionic bonding , amine gas treating , metastability , polymer , materials science , electrolyte , polymerization , bistability , chemical engineering , polymer chemistry , diode , base (topology) , chemistry , ion , organic chemistry , electrode , composite material , optoelectronics , mathematical analysis , mathematics , engineering
A highly rigid amine‐based polymer of intrinsic microporosity (PIM), prepared by a polymerization reaction involving the formation of Tröger’s base, is demonstrated to act as an ionic diode with electrolyte‐dependent bistable switchable states.