Near‐IR‐Triggered, Remote‐Controlled Release of Metal Ions: A Novel Strategy for Caged Ions | Zendy

Atilgan Ahmet | Zendy; Tanriverdi Eçik Esra | Zendy; Guliyev Ruslan | Zendy; Uyar T. Bilal | Zendy; ErbasCakmak Sundus | Zendy; Akkaya Engin U. | Zendy

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Near‐IR‐Triggered, Remote‐Controlled Release of Metal Ions: A Novel Strategy for Caged Ions

Author(s) -

Atilgan Ahmet,

Tanriverdi Eçik Esra,

Guliyev Ruslan,

Uyar T. Bilal,

ErbasCakmak Sundus,

Akkaya Engin U.

Publication year - 2014

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201405462

Subject(s) - moiety , singlet oxygen , photosensitizer , ion , metal ions in aqueous solution , photochemistry , metal , chemistry , irradiation , cleavage (geology) , ligand (biochemistry) , oxygen , materials science , stereochemistry , organic chemistry , receptor , biochemistry , physics , fracture (geology) , nuclear physics , composite material

A ligand incorporating a dithioethenyl moiety is cleaved into fragments which have a lower metal‐ion affinity upon irradiation with low‐energy red/near‐IR light. The cleavage is a result of singlet oxygen generation which occurs on excitation of the photosensitizer modules. The method has many tunable factors that could make it a satisfactory caging strategy for metal ions.

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