The IX (X=O,N,C) Double Bond in Hypervalent Iodine Compounds: Is it Real? | Zendy

Ivanov Alexander S. | Zendy; Popov Ivan A. | Zendy; Boldyrev Alexander I. | Zendy; Zhdankin Viktor V. | Zendy

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The IX (X=O,N,C) Double Bond in Hypervalent Iodine Compounds: Is it Real?

Author(s) -

Ivanov Alexander S.,

Popov Ivan A.,

Boldyrev Alexander I.,

Zhdankin Viktor V.

Publication year - 2014

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201405142

Subject(s) - hypervalent molecule , iodine , chemistry , computational chemistry , crystallography , organic chemistry

IX (X=O, N, C) bonding was analyzed in the related hypervalent iodine compounds based on the adaptive natural density partitioning (AdNDP) approach. The results confirm the presence of a I→X σ dative bond, as opposed to the widely used IX notation. A clear formulation of the electronic structure of these hypervalent iodine compounds would be useful in establishing reaction mechanisms and electronic structures in bioinorganic problems of general applicability.

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