BH, CH, and BC Bond Activation: The Role of Two Adjacent Agostic Interactions | Zendy

Cassen Audrey | Zendy; Gloaguen Yann | Zendy; Vendier Laure | Zendy; Duhayon Carine | Zendy; PobladorBahamonde Amalia | Zendy; Raynaud Christophe | Zendy; Clot Eric | Zendy; Alcaraz Gilles | Zendy; SaboEtienne Sylviane | Zendy

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BH, CH, and BC Bond Activation: The Role of Two Adjacent Agostic Interactions

Author(s) -

Cassen Audrey,

Gloaguen Yann,

Vendier Laure,

Duhayon Carine,

PobladorBahamonde Amalia,

Raynaud Christophe,

Clot Eric,

Alcaraz Gilles,

SaboEtienne Sylviane

Publication year - 2014

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201404753

Subject(s) - agostic interaction , chemistry , reactivity (psychology) , boranes , ruthenium , stereochemistry , linker , polarity (international relations) , crystallography , boron , catalysis , metal , organic chemistry , medicine , biochemistry , alternative medicine , pathology , computer science , cell , operating system

Tuning the nature of the linker in a L∼BHR phosphinoborane compound led to the isolation of a ruthenium complex stabilized by two adjacent, δ‐CH and ε‐B sp2 H, agostic interactions. Such a unique coordination mode stabilizes a 14‐electron “RuH 2 P 2 ” fragment through connected σ‐bonds of different polarity, and affords selective BH, CH, and BC bond activation as illustrated by reactivity studies with H 2 and boranes.

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