Accessing Zinc Monohydride Cations through Coordinative Interactions | Zendy

Lummis Paul A. | Zendy; Momeni Mohammad R. | Zendy; Lui Melanie W. | Zendy; McDonald Robert | Zendy; Ferguson Michael J. | Zendy; Miskolzie Mark | Zendy; Brown Alex | Zendy; Rivard Eric | Zendy

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Accessing Zinc Monohydride Cations through Coordinative Interactions

Author(s) -

Lummis Paul A.,

Momeni Mohammad R.,

Lui Melanie W.,

McDonald Robert,

Ferguson Michael J.,

Miskolzie Mark,

Brown Alex,

Rivard Eric

Publication year - 2014

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201404611

Subject(s) - electrophile , chemistry , nucleophile , zinc , carbene , hydride , hydrosilylation , catalysis , ring (chemistry) , combinatorial chemistry , medicinal chemistry , photochemistry , organic chemistry , hydrogen

We present isolable examples of formal zinc hydride cations supported by N‐heterocyclic carbene (NHC) donors, and investigate the dual electrophilic and nucleophilic (hydridic) character of the encapsulated [ZnH] + units by computational methods and preliminary hydrosilylation catalysis.

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