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Cross‐Coupling Reactions between Stable Carbenes
Author(s) -
Weinstein Cory M.,
Martin Caleb D.,
Liu Liu Leo,
Bertrand Guy
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201404199
Subject(s) - carbene , allene , chemistry , nucleophile , bent molecular geometry , coupling (piping) , transition metal carbene complex , coupling reaction , photochemistry , computational chemistry , organic chemistry , materials science , catalysis , metallurgy
By utilizing stable carbenes with low‐lying LUMOs, coupling with the stable nucleophilic diaminocyclopropenylidene was achieved. This reaction resulted in the formation of two new and rare examples of a bent allene as well as the isolation of the first carbene–carbene heterodimer.