Premium
Ultrahigh‐Resolution NMR Spectroscopy
Author(s) -
Foroozandeh Mohammadali,
Adams Ralph W.,
Meharry Nicola J.,
Jeannerat Damien,
Nilsson Mathias,
Morris Gareth A.
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201404111
Subject(s) - homonuclear molecule , spectroscopy , nuclear magnetic resonance spectroscopy , chemistry , decoupling (probability) , nuclear magnetic resonance , resolution (logic) , spectral line , analytical chemistry (journal) , materials science , physics , molecule , organic chemistry , computer science , quantum mechanics , control engineering , artificial intelligence , astronomy , engineering
All psyched up : A flexible and general pure shift experiment (PSYCHE) has been developed that offers superior sensitivity, spectral purity, and tolerance of strong coupling over existing methods for broadband homonuclear decoupling. The partial spectra of estradiol in [D 6 ]DMSO obtained by normal 1 H NMR spectroscopy and PSYCHE are shown for comparison.