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Preparation of CO 2 /Diene Copolymers: Advancing Carbon Dioxide Based Materials
Author(s) -
Fiorani Giulia,
Kleij Arjan W.
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201403969
Subject(s) - telomerization , copolymer , diene , polymerization , polymer , carbon dioxide , materials science , catalysis , polymer chemistry , monomer , palladium , metastability , chemical engineering , chemistry , organic chemistry , composite material , natural rubber , engineering
CO 2 ‐based materials : Metastable CO 2 /diene‐based lactones, which were prepared by the palladium‐catalyzed telomerization of CO 2 and dienes, easily undergo aerobic radical homo‐polymerization to give novel CO 2 ‐rich polymers. This two‐step reaction set‐up expands the potential applications of CO 2 ‐based copolymers by adding innovative compositions, structures, and properties.