Preparation of CO 2 /Diene Copolymers: Advancing Carbon Dioxide Based Materials | Zendy

Fiorani Giulia | Zendy; Kleij Arjan W. | Zendy

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Preparation of CO 2 /Diene Copolymers: Advancing Carbon Dioxide Based Materials

Author(s) -

Fiorani Giulia,

Kleij Arjan W.

Publication year - 2014

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201403969

Subject(s) - telomerization , copolymer , diene , polymerization , polymer , carbon dioxide , materials science , catalysis , polymer chemistry , monomer , palladium , metastability , chemical engineering , chemistry , organic chemistry , composite material , natural rubber , engineering

CO 2 ‐based materials : Metastable CO 2 /diene‐based lactones, which were prepared by the palladium‐catalyzed telomerization of CO 2 and dienes, easily undergo aerobic radical homo‐polymerization to give novel CO 2 ‐rich polymers. This two‐step reaction set‐up expands the potential applications of CO 2 ‐based copolymers by adding innovative compositions, structures, and properties.

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