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Oxidative Catalysis Using the Stoichiometric Oxidant as a Reagent: An Efficient Strategy for Single‐Electron‐Transfer‐Induced Tandem Anion–Radical Reactions
Author(s) -
Kafka František,
Holan Martin,
Hidasová Denisa,
Pohl Radek,
Císařová Ivana,
Klepetářová Blanka,
Jahn Ullrich
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201403776
Subject(s) - tandem , chemistry , reagent , catalysis , electron transfer , conjugate , oxidative phosphorylation , stoichiometry , combinatorial chemistry , photochemistry , ion , radical ion , organic chemistry , biochemistry , materials science , composite material , mathematical analysis , mathematics
Oxidative single‐electron transfer‐catalyzed tandem reactions consisting of a conjugate addition and a radical cyclization are reported, which incorporate the mandatory terminal oxidant as a functionality into the product.