An Isolated Nitridyl Radical‐Bridged {Rh(N . )Rh} Complex | Zendy

Gloaguen Yann | Zendy; Rebreyend Christophe | Zendy; Lutz Martin | Zendy; Kumar Pravin | Zendy; Huber Martina | Zendy; van der Vlugt Jarl Ivar | Zendy; Schneider Sven | Zendy; de Bruin Bas | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

An Isolated Nitridyl Radical‐Bridged {Rh(N . )Rh} Complex

Author(s) -

Gloaguen Yann,

Rebreyend Christophe,

Lutz Martin,

Kumar Pravin,

Huber Martina,

van der Vlugt Jarl Ivar,

Schneider Sven,

de Bruin Bas

Publication year - 2014

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201403445

Subject(s) - chemistry , deprotonation , methylene , rhodium , crystallography , stereochemistry , photochemistry , medicinal chemistry , catalysis , organic chemistry , ion

Photochemical activation of [(PNN H )Rh(N 3 )] (PNN H =6‐di‐( tert ‐butyl)phosphinomethyl‐2,2′‐bipyridine) complex 2 produced the paramagnetic (S=1/2), [(PNN)RhN . ‐Rh(PNN)] complex 3 (PNN − =methylene‐deprotonated PNN H ), which could be crystallographically characterized. Spectroscopic investigation of 3 indicates a predominant nitridyl radical ( . N 2− ) character, which was confirmed computationally. Complex 3 reacts selectively with CO, producing two equivalents of [(PNN)Rh I (CO)] complex 4 , presumably by nitridyl radical N,N‐coupling.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research