Hydrogenation of Sulfoxides to Sulfides under Mild Conditions Using Ruthenium Nanoparticle Catalysts | Zendy

Mitsudome Takato | Zendy; Takahashi Yusuke | Zendy; Mizugaki Tomoo | Zendy; Jitsukawa Koichiro | Zendy; Kaneda Kiyotomi | Zendy

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Hydrogenation of Sulfoxides to Sulfides under Mild Conditions Using Ruthenium Nanoparticle Catalysts

Author(s) -

Mitsudome Takato,

Takahashi Yusuke,

Mizugaki Tomoo,

Jitsukawa Koichiro,

Kaneda Kiyotomi

Publication year - 2014

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201403425

Subject(s) - catalysis , ruthenium , nanoparticle , redox , chemistry , atmospheric pressure , reaction conditions , inorganic chemistry , materials science , organic chemistry , nanotechnology , oceanography , geology

The first demonstration of the hydrogenation of sulfoxides under atmospheric H 2 pressure is reported. The highly efficient reaction is facilitated by a heterogeneous Ru nanoparticle catalyst. The mild reaction conditions enable the selective hydrogenation of a wide range of functionalized sulfoxides to the corresponding sulfides. The high redox ability of RuO x nanoparticles plays a key role in the hydrogenation.

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