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Accessing the Single‐Electron Manifold: Magnesium‐mediated Hydrogen Release from Silanes
Author(s) -
Liptrot David J.,
Hill Professor Michael S.,
Mahon Mary F.
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201403208
Subject(s) - silanes , hydride , hydrogen , magnesium , redox , metathesis , catalysis , chemistry , inorganic chemistry , organic chemistry , polymerization , silane , polymer
Reactions of TEMPO (2,2,6,6‐tetramethyl‐1‐piperidinyloxy) with magnesium hydride species initiate oxidative hydrogen release, which may be elaborated to a catalytic regime within a manifold constructed about sequential TEMPO‐mediated redox and MgO/SiH metathesis processes.
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