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Gold‐Catalyzed 1,2‐Oxoarylations of Nitriles with Pyridine‐Derived Oxides
Author(s) -
Karad Somnath Narayan,
Liu RaiShung
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201403015
Subject(s) - catalysis , pyridine , chemistry , medicinal chemistry , organic chemistry
We report the first success in the gold‐catalyzed oxoarylations of nitriles with pyridine‐derived N ‐oxides using gold carbenes as initiators. These oxoarylations were also achieved satisfactorily in intermolecular three‐component oxidations, including diverse alkenyldiazo esters, nitriles, and pyridine‐based oxides.