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Synthesis of Long‐Sought C 66 with Exohedral Stabilization
Author(s) -
Gao CongLi,
Li Xiang,
Tan YuanZhi,
Wu XinZhou,
Zhang Qianyan,
Xie SuYuan,
Huang RongBin
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201402625
Subject(s) - fullerene , carbon atom , derivatization , aromaticity , carbon fibers , crystallography , stereochemistry , chemistry , materials science , molecule , organic chemistry , ring (chemistry) , composite material , high performance liquid chromatography , composite number
Previously reported fused‐pentagon fullerenes stabilized by exohedral derivatization do not share the same cage with those stabilized by endohedral encapsulation. Herein we report the crystallographic identification of #4348 C 66 Cl 10 , which has the same cage as that of previously reported Sc 2 @C 66 . According to the geometrical data of #4348 C 66 Cl 10 , both strain relief (at the fused pentagons) and local aromaticity (on the remaining sp 2 ‐hybrided carbon framework) contribute to the exohedral stabilization of this long‐sought 66 carbon atom cage.