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Back Cover: Large Zero‐Field Splittings of the Ground Spin State Arising from Antisymmetric Exchange Effects in Heterometallic Triangles (Angew. Chem. Int. Ed. 21/2014)
Author(s) -
Magee Samantha A.,
Sproules Stephen,
Barra AnneLaure,
Timco Grigore A.,
Chilton Nicholas F.,
Collison David,
Winpenny Richard E. P.,
McInnes Eric J. L.
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201401141
Subject(s) - antisymmetric relation , cover (algebra) , ground state , antisymmetry , condensed matter physics , physics , spin (aerodynamics) , state (computer science) , crystallography , chemistry , mathematics , quantum mechanics , mathematical physics , engineering , algorithm , thermodynamics , philosophy , mechanical engineering , linguistics
The antisymmetric component of the electronic exchange interaction (also known as Dzyaloshinski–Moriya exchange) is often overlooked in modeling the magnetic data of molecular species, but in the Communication by E. J. L. McInnes and co‐workers on page 5310 ff., it is shown to be responsible for the large magnetic anisotropy in the S =5/2 ground state of a trimetallic complex. The illustration plays on the concept of “antisymmetry” and triangles with an Escher triangle.