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CO/C‐H as an Acylating Reagent: A Palladium‐Catalyzed Aerobic Oxidative Carbonylative Esterification of Alcohols
Author(s) -
Wang Lu,
Wang Yanxia,
Liu Chao,
Lei Aiwen
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201400612
Subject(s) - reagent , catalysis , chemistry , palladium , olefin fiber , oxidative phosphorylation , ligand (biochemistry) , organic chemistry , carbonylation , substrate (aquarium) , acylation , combinatorial chemistry , carbon monoxide , receptor , biochemistry , geology , oceanography
A palladium‐catalyzed oxidative carbonylative esterification of a variety of functionalized alcohols under base‐ and ligand‐free conditions has been demonstrated. A CO/olefin combination was utilized as the acylating reagent with O 2 as a benign oxidant. Notably, the scope of the substrate alcohols has been greatly broadened.