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A Scalable Rhodium‐Catalyzed Intermolecular Aziridination Reaction
Author(s) -
Smith David T.,
Njardarson Jon T.
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201400502
Subject(s) - rhodium , aziridine , amine gas treating , catalysis , styrene , intermolecular force , chemistry , organic chemistry , polymer chemistry , combinatorial chemistry , polymer , copolymer , molecule , ring (chemistry)
The amine has landed ! By employing the rhodium catalyst [Rh 2 (esp) 2 ] in the presence of a readily available amine source (DPH), unactivated and styrene‐type olefins can now be stereospecifally transformed, in high yields at room temperature, into valuable NH aziridine products. esp=α,α,α′,α′‐tetramethyl‐1,3‐benzenedipropionic acid.