Asymmetric Catalysis on the Nanoscale: The Organocatalytic Approach to Helicenes | Zendy

Kötzner Lisa | Zendy; Webber Matthew J. | Zendy; Martínez Alberto | Zendy; De Fusco Claudia | Zendy; List Benjamin | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Asymmetric Catalysis on the Nanoscale: The Organocatalytic Approach to Helicenes

Author(s) -

Kötzner Lisa,

Webber Matthew J.,

Martínez Alberto,

De Fusco Claudia,

List Benjamin

Publication year - 2014

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201400474

Subject(s) - enantioselective synthesis , phosphoric acid , organocatalysis , catalysis , chemistry , combinatorial chemistry , nanoscopic scale , indole test , organic chemistry , stereochemistry , nanotechnology , materials science

The first asymmetric organocatalytic synthesis of helicenes is reported. A novel SPINOL‐derived phosphoric acid, bearing extended π‐substituents, catalyzes the asymmetric synthesis of helicenes through an enantioselective Fischer indole reaction. A variety of azahelicenes and diazahelicenes could be obtained with good to excellent yields and enantioselectivities.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research