Size‐Selective Complexation and Extraction of Endohedral Metallofullerenes with Cycloparaphenylene | Zendy

Nakanishi Yusuke | Zendy; Omachi Haruka | Zendy; Matsuura Sanae | Zendy; Miyata Yasumitsu | Zendy; Kitaura Ryo | Zendy; Segawa Yasutomo | Zendy; Itami Kenichiro | Zendy; Shinohara Hisanori | Zendy

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Size‐Selective Complexation and Extraction of Endohedral Metallofullerenes with Cycloparaphenylene

Author(s) -

Nakanishi Yusuke,

Omachi Haruka,

Matsuura Sanae,

Miyata Yasumitsu,

Kitaura Ryo,

Segawa Yasutomo,

Itami Kenichiro,

Shinohara Hisanori

Publication year - 2014

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201311268

Subject(s) - metallofullerene , extraction (chemistry) , fullerene , chemistry , combinatorial chemistry , chromatography , organic chemistry

A new strategy for the non‐chromatographic extraction of metallofullerenes from solutions of arc‐processed raw soot is based on the size‐selective complexation with cycloparaphenylene (CPP). [11]CPP has a high affinity for M x @C 82 ( x =1, 2); for example, Gd@C 82 can be selectively extracted from a fullerene mixture by the addition of [11]CPP. This approach should open new opportunities in metallofullerene chemistry, including for the bulk extraction of metallofullerenes.

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