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Size‐Selective Complexation and Extraction of Endohedral Metallofullerenes with Cycloparaphenylene
Author(s) -
Nakanishi Yusuke,
Omachi Haruka,
Matsuura Sanae,
Miyata Yasumitsu,
Kitaura Ryo,
Segawa Yasutomo,
Itami Kenichiro,
Shinohara Hisanori
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201311268
Subject(s) - metallofullerene , extraction (chemistry) , fullerene , chemistry , combinatorial chemistry , chromatography , organic chemistry
A new strategy for the non‐chromatographic extraction of metallofullerenes from solutions of arc‐processed raw soot is based on the size‐selective complexation with cycloparaphenylene (CPP). [11]CPP has a high affinity for M x @C 82 ( x =1, 2); for example, Gd@C 82 can be selectively extracted from a fullerene mixture by the addition of [11]CPP. This approach should open new opportunities in metallofullerene chemistry, including for the bulk extraction of metallofullerenes.