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Construction of Mesoporous Frameworks with Vanadoborate Clusters
Author(s) -
Chen Hong,
Yu ZhengBao,
Bacsik Zoltán,
Zhao Huishuang,
Yao Qingxia,
Sun Junliang
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201311122
Subject(s) - mesoporous material , chemistry , catalysis , biochemistry
A new porous vanadoborate was synthesized by employing the scale chemistry theory with the vanadoborate cluster V 10 B 28 . The twofold interpenetrated lvt network was assembled with zinc‐containing elliptical vanadoborate clusters and Zn polyhedra. The single lvt framework contains a three‐dimensional 38×38×20 ring channel system with the pore size (24.7×12.7 Å) reaching the mesoscale, thus indicating the possibility of constructing 3D ordered mesopores with vanadoborate clusters. The porosity of the SUT‐7 structure was confirmed by CO 2 adsorption of the as‐synthesized materials.