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Towards True Carbaporphyrinoids: Synthesis of 21‐Carba‐23‐thiaporphyrin
Author(s) -
Berlicka Anna,
Dutka Paweł,
Szterenberg Ludmiła,
LatosGrażyński Lechosław
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201310999
Subject(s) - synthon , moiety , cyclopentadienyl complex , palladium , core (optical fiber) , stereochemistry , chemistry , combinatorial chemistry , computer science , organic chemistry , catalysis , telecommunications
In the search for porphyrinoids with a built‐in cyclopentadienyl moiety (true carbaporphyrins), a rational synthesis of carbathiaporphyrin, the synthons, has been elaborated. The donors (C,N,S,N) in the porphyrinic core of carbathiaporphyrinoids are potentially of fundamental importance for generating organometallic complexes, as exemplified through formation of the palladium(II) complex.