Premium
Fluorocarbons Modulate the Coordination Sphere of f‐Element Complexes
Author(s) -
Alvarez Santiago,
Menjón Babil
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201310916
Subject(s) - polyhedron , coordination sphere , distortion (music) , element (criminal law) , affect (linguistics) , chemistry , stereochemistry , crystallography , computer science , communication , psychology , geometry , mathematics , political science , crystal structure , telecommunications , amplifier , law , bandwidth (computing)
Weak yet influential : Fluorocarbons, the least coordinating of all halocarbons, establish secondary coordinative interactions with f elements. These interactions affect the stereochemistry of the complexes and provide examples of coordination polyhedra along distortion paths not seen before (see graphic).