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A Brønsted Acid Catalyzed Redox Arylation
Author(s) -
Peng Bo,
Huang Xueliang,
Xie LanGui,
Maulide Nuno
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201310865
Subject(s) - redox , catalysis , brønsted–lowry acid–base theory , chemistry , aryl , combinatorial chemistry , transformation (genetics) , metal , atom (system on chip) , organic chemistry , computer science , biochemistry , embedded system , alkyl , gene
A Brønsted acid catalyzed redox arylation of ynamides that employs aryl sulfoxides as the arylating agents is reported. This metal‐free transformation proceeds at room temperature and efficiently affords α‐arylated oxazolidinones in a redox‐neutral, atom‐economic fashion.