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Rapid Selective Electrocatalytic Reduction of Carbon Dioxide to Formate by an Iridium Pincer Catalyst Immobilized on Carbon Nanotube Electrodes
Author(s) -
Kang Peng,
Zhang Sheng,
Meyer Thomas J.,
Brookhart Maurice
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201310722
Subject(s) - formate , catalysis , carbon nanotube , iridium , inorganic chemistry , electrode , electrocatalyst , electrochemical reduction of carbon dioxide , nanotube , aqueous solution , chemistry , covalent bond , chemical engineering , materials science , electrochemistry , pincer movement , nanotechnology , organic chemistry , carbon monoxide , engineering
An iridium pincer dihydride catalyst was immobilized on carbon nanotube‐coated gas diffusion electrodes (GDEs) by using a non‐covalent binding strategy. The as‐prepared GDEs are efficient, selective, durable, gas permeable electrodes for electrocatalytic reduction of CO 2 to formate. High turnover numbers (ca. 54 000) and turnover frequencies (ca. 15 s −1 ) were enabled by the novel electrode architecture in aqueous solutions saturated in CO 2 with added HCO 3 − .