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Creating Added Value with a Waste: Methylation of Amines with CO 2 and H 2
Author(s) -
Tlili Anis,
Frogneux Xavier,
Blondiaux Enguerrand,
Cantat Thibault
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201310337
Subject(s) - value (mathematics) , chemistry , waste management , environmental chemistry , mathematics , statistics , engineering
Unknown before 2013 , a novel methodology utilizes CO 2 as a carbon source for the methylation of amines, with water as the by‐product. This strategy offers a sustainable route to methylamines by converting CO 2 to value‐added chemicals, using molecular hydrogen as a cheap and renewable reductant. The method may open novel applications for recycling CO 2 to bulk and fine chemicals.
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