Inside Cover: Kinetic Resolution of Allyl Fluorides by Enantioselective Allylic Trifluoromethylation Based on Silicon‐Assisted CF Bond CleavageZ308071 (Angew. Chem. Int. Ed. 2/2014) | Zendy

Nishimine Takayuki | Zendy; Fukushi Kazunobu | Zendy; Shibata Naoyuki | Zendy; Taira Hiromi | Zendy; Tokunaga Etsuko | Zendy; Yamano Akihito | Zendy; Shiro Motoo | Zendy; Shibata Norio | Zendy

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Inside Cover: Kinetic Resolution of Allyl Fluorides by Enantioselective Allylic Trifluoromethylation Based on Silicon‐Assisted CF Bond CleavageZ308071 (Angew. Chem. Int. Ed. 2/2014)

Author(s) -

Nishimine Takayuki,

Fukushi Kazunobu,

Shibata Naoyuki,

Taira Hiromi,

Tokunaga Etsuko,

Yamano Akihito,

Shiro Motoo,

Shibata Norio

Publication year - 2014

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201309818

Subject(s) - enantioselective synthesis , allylic rearrangement , kinetic resolution , hydrosilylation , cinchona , trifluoromethylation , silicon , chemistry , catalysis , stereochemistry , organic chemistry , alkyl , trifluoromethyl

The first kinetic resolution of allyl fluorides was achieved by an enantioselective allylic trifluoromethylation that is catalyzed by a bis(cinchona alkaloid), as described by N. Shibata et al. in their Communication on page 517 ff. Two kinds of chiral fluorinated compounds, which incorporate C*F and C*CF 3 units, respectively, can thus be accessed by a single transformation. Painting: “Mori” (“Forest”) by Mami Shibata; the way through a forest can lead to something exciting.

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