Crystal Engineering of an nbo Topology Metal–Organic Framework for Chemical Fixation of CO 2  under Ambient Conditions | Zendy

Gao WenYang | Zendy; Chen Yao | Zendy; Niu Youhong | Zendy; Williams Kia | Zendy; Cash Lindsay | Zendy; Perez Pastor J. | Zendy; Wojtas Lukasz | Zendy; Cai Jianfeng | Zendy; Chen YuSheng | Zendy; Ma Shengqian | Zendy

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Crystal Engineering of an nbo Topology Metal–Organic Framework for Chemical Fixation of CO 2 under Ambient Conditions

Author(s) -

Gao WenYang,

Chen Yao,

Niu Youhong,

Williams Kia,

Cash Lindsay,

Perez Pastor J.,

Wojtas Lukasz,

Cai Jianfeng,

Chen YuSheng,

Ma Shengqian

Publication year - 2014

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201309778

Subject(s) - natural bond orbital , crystal engineering , topology (electrical circuits) , metal , materials science , crystal (programming language) , metal organic framework , crystal structure , chemistry , crystallography , computer science , metallurgy , organic chemistry , mathematics , molecule , combinatorics , adsorption , supramolecular chemistry , programming language

Crystal engineering of the nbo metal–organic framework (MOF) platform MOF‐505 with a custom‐designed azamacrocycle ligand (1,4,7,10‐tetrazazcyclododecane‐ N , N ′, N ′′, N ′′′‐tetra‐ p ‐methylbenzoic acid) leads to a high density of well‐oriented Lewis active sites within the cuboctahedral cage in MMCF‐2, [Cu 2 (Cu‐tactmb)(H 2 O) 3 (NO 3 ) 2 ]. This MOF demonstrates high catalytic activity for the chemical fixation of CO 2 into cyclic carbonates at room temperature under 1 atm pressure.

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