Premium
Non‐Pyrolytic, Large‐Scale Synthesis of Trichalcogenasumanene: A Two‐Step Approach
Author(s) -
Li Xuexiang,
Zhu Yongtao,
Shao Jiafeng,
Wang Baolin,
Zhang Shangxi,
Shao Yongliang,
Jin Xiaojie,
Yao Xiaojun,
Fang Ran,
Shao Xiangfeng
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201308781
Subject(s) - pyrolytic carbon , scale (ratio) , solid state , ring (chemistry) , nanotechnology , chemistry , materials science , combinatorial chemistry , organic chemistry , pyrolysis , physics , quantum mechanics
Trichalcogenasumanenes were synthesized on a multigram scale through a two‐step approach that takes advantage of non‐pyrolytic cyclization and solventless ring contraction. Solid‐state structure and photophysical investigations demonstrate that these compounds are promising candidates for electronic materials.